In Orthodox theology the baptismal robe symbolizes the "Garments of Light" (i.e., the fullness of Divine grace) with which Adam and Eve were clothed in the Garden of Eden before the Fall of Man. Baptism is believed to cleanse the believer of all the sinful defilements both of original sin and personal sins and the white garment is symbolic of this. During the ektenia (litany) before baptism, the deacon prays "That he (she) may preserve this (her) baptismal garment and the earnest of the Spirit pure and undefiled unto the dead Day of Christ our God...", referring not so much to the material garment as to the spiritual cleansing it represents.
He then sprinkles the newly-baptized with water and washes all of the places the chrism was applied, and performs the tonsure.
